Frontispiece: Remote Fluorination and Fluoroalkyl(thiol)ation Reactions
نویسندگان
چکیده
منابع مشابه
Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions
1. INTRODUCTION Despite being largely absent from natural products and biological processes, fluorine plays a conspicuous and increasingly important role within pharmaceuticals and agro-chemicals, as well as in materials science. 1a−c Indeed, as many as 35% of agrochemicals and 20% of pharmaceuticals on the market contain fluorine. 1d Fluorine is the most electronegative element in the periodic...
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Stereoselective synthesis of two fluorine-bearing drug-like scaffolds, dihydroquinazolone and benzooxazinone, has been accomplished through asymmetric fluorocyclization reactions initiated by the fluorination process. The reaction employs double axially chiral anionic phase-transfer catalysts to achieve high diastereo- and enantioselectivities, and a wide range of fluorine-containing dihydroqui...
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Ando, et a!., Direct interaction of elemental fluorine with diamond surfaces, Diamond and Related Materials 1996; 5: 1021-1025.* Kealey, et a!., Fluorination of polycrystalline diamond films and powders. An investigation using FTIR spectroscopy, SEM, energyfiltered TEM, XPS and fluorine-IS radiotracer methods, J. Mater. Chern. 2001; 11: 879-886.* Liu, et a!., Functionalization of Nanoscale Diam...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2020
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.202086762